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Sku SC26-1268_100_MG
US-Strem
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Product Information

Product Name
(R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-1-(di-t-butylphosphino)ethylferrocene, min. 97% JoSPOphos
Brand Name
US-Strem
Product Number
26-1268
CAS
1221746-56-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71311019
IUPAC Name
(Z)-tert-butyl-2-(1R)-1-ditert-butylphosphanylethylcyclopenta-2,4-dien-1-ylidene-oxidophosphanium;cyclopenta-1,3-diene;iron(2+)
InChI Key
RMJTVESITBPOLN-FMOMHUKBSA-N
SMILES
CC@H(C\1=CC=C/C1=P+(\C(C)(C)C)/O-)P(C(C)(C)C)C(C)(C)C.CH-1C=CC=C1.Fe+2

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes: 1.Chiral mixed secondary phosphine-oxide -phosphines: High-performing and easily accessible ligands for asymmetric hydrogenation.
2.Cobalt precursors for high-throughput discovery of base metal asymmetric alkene hydrogenation catalysts. 3.Regioconvergent and enantioselective rhodium-catalyzed hydroamination of internal and terminal alkynes: A highly flexible access to chiral pyrazoles.
4.Ligand for Ru-catalyzed Asymmetric Hydrogenation of Tetrasubstituted Acrylates .