Product Name
(R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-1-(di-t-butylphosphino)ethylferrocene, min. 97% JoSPOphos
Certificate of Analysis (COA)
IUPAC Name
(Z)-tert-butyl-2-(1R)-1-ditert-butylphosphanylethylcyclopenta-2,4-dien-1-ylidene-oxidophosphanium;cyclopenta-1,3-diene;iron(2+)
InChI Key
RMJTVESITBPOLN-FMOMHUKBSA-N
SMILES
CC@H(C\1=CC=C/C1=P+(\C(C)(C)C)/O-)P(C(C)(C)C)C(C)(C)C.CH-1C=CC=C1.Fe+2
Technical Notes:
1.Chiral mixed secondary phosphine-oxide -phosphines: High-performing and easily accessible ligands for asymmetric hydrogenation.
2.Cobalt precursors for high-throughput discovery of base metal asymmetric alkene hydrogenation catalysts. 3.Regioconvergent and enantioselective rhodium-catalyzed hydroamination of internal and terminal alkynes: A highly flexible access to chiral pyrazoles.
4.Ligand for Ru-catalyzed Asymmetric Hydrogenation of Tetrasubstituted Acrylates .