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{(R)-(+)-7-[N-(1,3-dithian-2-yl)methylamino]-7'-[bis(3,5-di-t-butylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane}chlorodihydroiridium(III), 97+% [Ir-(R)-DTB-SpiroSAP]|77-2510|2055233-32-2

{(R)-(+)-7-[N-(1,3-dithian-2-yl)methylamino]-7'-[bis(3,5-di-t-butylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane}chlorodihydroiridium(III), 97+% [Ir-(R)-DTB-SpiroSAP]

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Sku SC77-2510_100_MG
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Product Information

Product Name
{(R)-(+)-7-N-(1,3-dithian-2-yl)methylamino-7'-bis(3,5-di-t-butylphenyl)phosphino-2,2',3,3'-tetrahydro-1,1'-spirobindane}chlorodihydroiridium(III), 97+% Ir-(R)-DTB-SpiroSAP
Brand Name
US-Strem
Product Number
77-2510
CAS
2055233-32-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
124220166
IUPAC Name
(3R)-4'-bis(3,5-ditert-butylphenyl)phosphanyl-N-(1,3-dithian-2-ylmethyl)-3,3'-spirobi1,2-dihydroindene-4-amine;chloro(dihydrido)iridium
InChI Key
KAKPWOOWQOQMTL-MXLXQPIMSA-M
SMILES
CC(C)(C)C1=CC(=CC(=C1)P(C2=CC=CC3=C2C@4(CCC5=C4C(=CC=C5)NCC6SCCCS6)CC3)C7=CC(=CC(=C7)C(C)(C)C)C(C)(C)C)C(C)(C)C.ClIrH2

Description

Technical Notes:
1. Catalyst used for the asymmetric hydrogenation of ß-alkyI- ß-ketoesters.
Reference:
1. Angew. Chem. Int. Ed., 2015, 54, 8791.