[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%|77-5074|1208092-27-6

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%

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Sku SC77-5074_500_MG
US-Strem
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Product Information

Product Name
(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole4-cyano-3-nitrobenzenecarboxylato1,2,3-n-2-propenyliridium(III), min. 97%
Brand Name
US-Strem
Product Number
77-5074
CAS
1208092-27-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
117065378
InChI Key
WNUGBSVEKALVKR-UHFFFAOYSA-N
SMILES
CH2CHCH2.C1OC2=C(O1)C(=C(C=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)C5=C(C=CC6=C5OCO6)P(C7=CC=CC=C7)C8=CC=CC=C8.C1=C-C(=CC(=C1C#N)N+(=O)O-)C(=O)O.Ir

Application

Tochnical Notes:
1. Catalyst used for the diastereo- and onantioselectlve carbonyl (trimethylsilyt)allylatlon from the
aconoi,or aldehyde, oxidation level.
2.Catalvst used for the diastereo- and enantioselective carbonyt (hydroxy)allyiation to form antl- 1,2-diols.
3. Catalyst used for the diastereo- and enantioselective carbony! (hydroxymethyl)allylatlon from the alcohol, or aldehyde,
4.Catalyst used for the diastereo- and enantioselective carbonyI tert-prenylation from the alcohol, or aldehyda, oxldatlon lovel. 5.Catalyst used for the diastereo- and enan tloselactive carbonyl double crotylation of 1,3-dlols.
6.Catalyst used for the dlastereo- and enantioselective carbony crotylation from the alcohot or aldehyde oxidation level