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Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]|46-0480|1445972-29-1

Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]

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Sku SC46-0480_250_MG
US-Strem
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Product Information

Product Name
Methanesulfonato2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% AdBrettPhos Palladacycle Gen. 3
Brand Name
US-Strem
Product Number
46-0480
CAS
1445972-29-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
155882747
IUPAC Name
bis(1-adamantyl)-3,6-dimethoxy-2-2,4,6-tri(propan-2-yl)phenylphenylphosphanium;methanesulfonic acid;palladium(2+);(2-phenylphenyl)azanide
InChI Key
MQXKPUBRAYCAQA-UHFFFAOYSA-O
SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C(C=CC(=C2PH+(C34CC5CC(C3)CC(C5)C4)C67CC8CC(C6)CC(C8)C7)OC)OC)C(C)C.CS(=O)(=O)O.C1=CC=C(C-=C1)C2=CC=CC=C2NH-.Pd+2

Application

Technical Notes:
1.Palladium catalyst used in the highly selective monoarylation of ammonia.
References:
1. Org.Lett., 2013, 15, 3734 . 2.ACS Catal., 2015, 5, 1386.