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Sku SC46-0388_250_MG
US-Strem
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Product Information

Product Name
Methanesulfonato9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), 98% Xantphos Palladacycle Gen. 4
Brand Name
US-Strem
Product Number
46-0388
CAS
1621274-19-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
156588434
IUPAC Name
4,5-bis(diphenylphosphanyl)-9,9-dimethylxanthene-1-sulfonate;N-methyl-2-phenylaniline;palladium(2+)
InChI Key
KOOVUEQXJMPHRD-UHFFFAOYSA-M
SMILES
CC1(C2=C(C(=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)OC5=C(C=CC(=C51)S(=O)(=O)O-)P(C6=CC=CC=C6)C7=CC=CC=C7)C.CNC1=CC=CC=C1C2=CC=CC=C-2.Pd+2

Application

Technical Notes:
1.Catalyst used in the aminocarbonylation of (hetero)aryl bromides.
2.Catalyst used in the aminocarbonylation of bromopyridine and alkyl-substituted bromobenzene.
References :
1. Org. L ett., 2014, 16, 4296.