CALLERY? (S)-Methyl oxazaborolidine, 1M in toluene|05-1001|112022-81-8

CALLERY? (S)-Methyl oxazaborolidine, 1M in toluene

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Product Information

Product Name
CALLERY? (S)-Methyl oxazaborolidine, 1M in toluene
Brand Name
US-Strem
Product Number
05-1001
CAS
112022-81-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734713
IUPAC Name
(3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo1,2-c1,3,2oxazaborole
InChI Key
VMKAFJQFKBASMU-KRWDZBQOSA-N
SMILES
B1(N2CCCC@H2C(O1)(C3=CC=CC=C3)C4=CC=CC=C4)C

Application

Technical Notes:
1. Convenient catalyst for the enantioselective borane reduction of ketones at am bient temperatures
2. Asymmetric synthesis of a chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines . 3.Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes andtriarylmethanes.
4. Enantioselective reduction of prochiral ketones with NaBH4/Me2S 4/(S)-Me CBS.
References: 1.Org.Lett.. 2014, 16, 5830.
2.J Am. Chem. Soc.. 2013. 135, 3307. 3.Synthetic Commun.. 2014, 44, 1515.

References Data Source From Pubchem

3,3,3-Trifluoroalanine
Publication Name: Science of Synthesis
Publication Date: 2025

Cyclolignan synthesis streamlined by enantioselective hydrogenation of tetrasubstituted olefins
Publication Name: Nature Synthesis
Publication Date: 2024-06-20
DOI: 10.1038/s44160-024-00564-y

Synthesis of nimbolide and its analogues and their application as poly(ADP-ribose) polymerase-1 trapping inducers
Publication Name: Nature Synthesis
Publication Date: 2023-11-27
DOI: 10.1038/s44160-023-00437-w

A neural network model informs the total synthesis of clovane sesquiterpenoids
Publication Name: Nature Synthesis
Publication Date: 2023-03-20
DOI: 10.1038/s44160-023-00271-0

Accelerated Asymmetric Reaction Screening with Optical Assays
Publication Name: Synthesis
Publication Date: 2022-02-25
DOI: 10.1055/a-1754-2271