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Sku SC07-1073_100_MG
US-Strem
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Product Information

Product Name
(4S,4'S)-2,2'-(4,6-Dibenzofurandiyl)bis4,5-dihydro-4-phenyloxazole, 98%
Brand Name
US-Strem
Product Number
07-1073
CAS
246040-77-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11224907
IUPAC Name
(4S)-4-phenyl-2-6-(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yldibenzofuran-4-yl-4,5-dihydro-1,3-oxazole
InChI Key
YNAUPJHAAOZVLV-CLJLJLNGSA-N
SMILES
C1C@@H(N=C(O1)C2=CC=CC3=C2OC4=C3C=CC=C4C5=NC@H(CO5)C6=CC=CC=C6)C7=CC=CC=C7

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1.Ligand for the Ni- catalyzed enantioselective addition of nitrones to activated cyclopropanes .
2.Ligand for the Zn-catalyzed Friedel-Crafts alkylation with a-substituted acrylates .
3.Ligand for the L ewis acid mediated enantioselective intramolecular redox reactions to generate ring-fusedtetrahydroquinolines.
4.Ligand for the L ews acid-catalyzed highly enantioselective a-cyanation with 4- acetyIphenyl cyanate.
5.Ligand for the Ni-catalyzed asymmetric 1 ,3-dipolar cycloaddition of ß-fluoroalkylated a,ß-Unsaturated 2- pyridylsulfones with nitrones to generate chiral fluoroalkylated isoxazolidines and y-amino alcohols.

References Data Source From Pubchem

Ascending of Cycloaddition Strategy for N–O Heterocycles

Publication Name: Synthesis
Publication Date: 2022-01-12
DOI: 10.1055/a-1703-6448

C–H Bond Functionalization of Amines: A Graphical Overview of Diverse Methods

Publication Name: SynOpen (2017)
Publication Date: 2021-07
DOI: 10.1055/s-0040-1706051

Effects of Chiral Ligands on the Asymmetric Carbonyl-Ene Reaction

Publication Name: Synlett
Publication Date: 2019-07-23
DOI: 10.1055/s-0037-1611875

Recent Advances in the Synthesis of β-Ketonitriles

Publication Name: Synthesis
Publication Date: 2017-11-07
DOI: 10.1055/s-0036-1589128

Fluoroalkylated Isoxazolidines by 1,3-Dipolar Cycloaddition

Publication Name: Synfacts
Publication Date: 2017-04-18
DOI: 10.1055/s-0036-1590243