2-((2S,3S)-3-(tert-Butyl)-4-(3,5-dicyclopentyl-2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)propan-2-ol, min. 97%, (99% ee) (2S,3S)-Baryphos|15-6911|2416226-68-9

2-((2S,3S)-3-(tert-Butyl)-4-(3,5-dicyclopentyl-2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)propan-2-ol, min. 97%, (99% ee) (2S,3S)-Baryphos

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Product Information

Product Name
2-((2S,3S)-3-(tert-Butyl)-4-(3,5-dicyclopentyl-2,6-dimethoxyphenyl)-2,3-dihydrobenzod1,3oxaphosphol-2-yl)propan-2-ol, min. 97%, (99% ee) (2S,3S)-Baryphos
Brand Name
US-Strem
Product Number
15-6911
CAS
2416226-68-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
155882729
IUPAC Name
2-(2S,3S)-3-tert-butyl-4-(3,5-dicyclopentyl-2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphol-2-ylpropan-2-ol
InChI Key
CHOYNURMAGXWEY-WLFXDIPCSA-N
SMILES
CC(C)(C)P@@1C@H(OC2=CC=CC(=C21)C3=C(C(=CC(=C3OC)C4CCCC4)C5CCCC5)OC)C(C)(C)O

Application

Technical notes:
1.Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
Reference:
1.J Am Chem. Soc 2020 142. 8036 8043

References Data Source From Pubchem

Atroposelective Suzuki–Miyaura Cross-Coupling of ortho-Sulfonyl-Substituted Aryls to Chiral Biaryls
Publication Name: Synfacts
Publication Date: 2022-11-17
DOI: 10.1055/s-0042-1753126