Bis(cyclopentadienyl)titanium dichloride, 99+% (Titanocene dichloride)|22-0200|1271-19-8

Bis(cyclopentadienyl)titanium dichloride, 99+% (Titanocene dichloride)

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Sku SC22-0200_25_G
US-Strem
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Product Information

Product Name
Bis(cyclopentadienyl)titanium dichloride, 99+% (Titanocene dichloride)
Brand Name
US-Strem
Product Number
22-0200
CAS
1271-19-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
76030824
IUPAC Name
bis(cyclopenta-1,3-diene);titanium(4+);dichloride
InChI Key
YMNCCEXICREQQV-UHFFFAOYSA-L
SMILES
CH-1C=CC=C1.CH-1C=CC=C1.Cl-.Cl-.Ti+4

Application

Technical Notes:
1.Precatalyst for reduction of esters and a, ß-unsaturated ketones.
2. Catalyzes reductive deoxygenation of alcohols and hydroxylamines. Catalyst for the radical cyclization of epoxides .
3.Reagent for the conversion of enynes to bicyclic cyclo pentenones. 5. Catalyzes silylation of alkenes and alkynes.
References:
1.J. Org. Chem., 1994, 59, 4323.
2.Org. L ett., 201 o, 12, 44.
3.J. Am. Chem. Soc., 2010, 132, 254.

References

New Titanocene (IV) Dicarboxylates with Potential Cytotoxicity: Synthesis, Structure, Stability and Electrochemistry
Publication Name: International Journal of Molecular Sciences
Publication Date: 2023-02-07
DOI: 10.3390/ijms24043340

Superstoichiometric Binding of the Anticancer Agent Titanocene Dichloride by Human Serum Transferrin and the Accompanying Lobe Closure
Publication Name: Biochemistry
Publication Date: 2022-04-04
DOI: 10.1021/acs.biochem.1c00813

Mass Spectrometric Evaluation of β-Cyclodextrins as Potential Hosts for Titanocene Dichloride
Publication Name: International Journal of Molecular Sciences
Publication Date: 2021-09-10
DOI: 10.3390/ijms22189789

Lewis Acid-Facilitated Radiofluorination of MN3PU: A LRRK2 Radiotracer
Publication Name: Molecules (Basel, Switzerland)
Publication Date: 2020-10-14
DOI: 10.3390/molecules25204710

Titanocene Selenide Sulfides Revisited: Formation, Stabilities, and NMR Spectroscopic Properties
Publication Name: Molecules (Basel, Switzerland)
Publication Date: 2019-01-16
DOI: 10.3390/molecules24020319