Organometallic chemistry, which examines the synthesis, structure, reactions, properties, and applications of metal-organic compounds, plays a pivotal role in advancing human society. Metal-organic compounds consist of a central metal atom surrounded by ligands, forming stable complexes with unique properties.
Among these, Carbolong Complexes stand out as an innovative class of planar conjugated carbon chains (with seven or more carbons) bonded to at least three carbon-metal atoms. These complexes were first synthesized and named in 2013 by Professor Xia Haiping's research group. This groundbreaking discovery has led to the development of carbolong complexes with original structures, excellent performance, and versatile applications.
Unique Features of Carbolong Complexes
Carbolong complexes are distinguished by their:
-
Rich Reactivity:
These complexes can undergo both pre-modification and post-derivatization, enabling the creation of various functional molecules. -
Diverse Applications:
Functionalized carbolong complexes have been effectively utilized in:- Light Energy Conversion
- Biomedicine
- Homogeneous Catalysis
- Oxygen Activation
This versatility makes them invaluable across multiple research and industrial fields.
Recommended products
| Product name | CAS | Item number |
|---|---|---|
| 8C Carbolong complex, 95% | 1667743-98-7 | 9307661 |
| 12C Carbolong complex, 95% | 2917610-83-2 | 9307662 |
| Carbolong peroxo complex, 95% | 2244156-01-0 | 9307663 |
| Os-Cu Carbolong complex, 95% | 2225872-98-8 | 9307664 |
| Phenanthroline-Carbolong, 95% | N/A | 9307665 |
Metal catalyst
| Product name | CAS | Item number |
|---|---|---|
| Dichlorobis(triphenylphosphine)palladium(II), 98% | 13965-03-2 | 242195 |
| Dicobalt octacarbonyl, 95% | 10210-68-1 | 533379 |
| 2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-3-chloropyridine complex, 98% | 1349182-65-5 | 9187355 |
Metal precursor
| Product name | CAS | Item number |
|---|---|---|
| Titanium(IV) chloride, 1 M solution in dichloromethane, J&KSeal | 7550-45-0 | 459124 |
| Vanadium(V) oxide, 99%, for synthesis | 1314-62-1 | 972308 |
| Zinc chloride, 98%, for analysis | 7646-85-7 | 975486 |
Ligand
| Product name | CAS | Item number |
|---|---|---|
| (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE | 824395-67-7 | 15-0474 |
| (4R,5R)-(-)-2,2-Dimethyl-4,5-bis((diphenylphosphino)methyl)-1,3-dioxolane, 98% | 32305-98-9 | 453464 |
| Triphenylphosphine, 99%, Cl:≤30 ppm | 603-35-0 | 993263 |
Azo and Diazo
| Product name | CAS | Item number |
|---|---|---|
| Ethyl diazoacetoacetate, 98% | 2009-97-4 | 460520 |
| Ethyl diazoacetate, 95% | 623-73-4 | 282677 |
Molecular building blocks
| Product name | CAS | Item number |
|---|---|---|
| Glycolic acid, 99% | 79-14-1 | 147016 |
| 3-Pentyn-1-ol, 98% | 10229-10-4 | 571781 |
| 3-Phenyl-1-propyne, 97%, stabilized | 10147-11-2 | 235212 |
Organometallic reagents
| Product name | CAS | Item number |
|---|---|---|
| 3,5-Dimethylphenylmagnesium bromide, 0.5 M solution in THF | 34696-73-6 | 911858 |
| n-Butyllithium, 1.6 M solution in hexanes, J&KSeal | 109-72-8 | 274232 |
| Vinylmagnesium bromide, 1.0 M solution in THF, J&KSeal | 1826-67-1 | 309166 |
Synthetic reagents
| Product name | CAS | Item number |
|---|---|---|
| Potassium tert-butoxide, 1.0 M solution in THF, J&KSeal | 865-47-4 | 962820 |
| Titanium(IV) isopropoxide, 98% | 546-68-9 | 162947 |
| 1,5,7-Triazabicyclo[4.4.0]dec-5-ene, 98% | 5807-14-7 | 478441 |
General product
| Product name | CAS | Item number |
|---|---|---|
| Potassium carbonate, 99% | 584-08-7 | 212583 |
| Sodium sulfate, 99%, anhydrous, for residue analysis | 7757-82-6 | 940131 |
| Dimethyl sulfoxide-d6, N/A, 99.8 atom%D, contains 0.03% v/v TMS | 2206-27-1 | 182473 |
向阳 翟
