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Sku SC14-1880_250_MG
US-Strem
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Product Information

Product Name
(1R,2R)-1,2-Cyclohexanediamino-N,N'-bis(4-bromobenzyl)allylchlorosilane, min. 98%
Brand Name
US-Strem
Product Number
14-1880
CAS
546084-25-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10415272
IUPAC Name
(3aR,7aR)-1,3-bis(4-bromophenyl)methyl-2-chloro-2-prop-2-enyl-3a,4,5,6,7,7a-hexahydrobenzod1,3,2diazasilole
InChI Key
JTYONYYNZDUUGN-DHIUTWEWSA-N
SMILES
C=CCSi1(N(C@@H2CCCCC@H2N1CC3=CC=C(C=C3)Br)CC4=CC=C(C=C4)Br)Cl

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1. A highly practical and enantioselective reagent for the allylation of aldehydes
2.The enantiodselective allylation and crotylation of dterically hindered and functionalized aryl ketones: Convenient success to unusual tertiary carbinol structures
References:
1. Angew. Chem. Int. Ed., 2003, 42, 946 2. Angew. Chem. Int. Ed.. 2006, 45, 3811

References

Tiacumicin B: An Antibiotic of Prime Importance and a Natural Product with an Inspiring Complex Structure

Publication Name: Synthesis
Publication Date: 2018-09-06
DOI: 10.1055/s-0037-1609933

Total Synthesis of Disorazole C1

Publication Name: Synfacts
Publication Date: 2015-01-19
DOI: 10.1055/s-0034-1379813