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Sku SC14-1815_1_G
US-Strem
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Product Information

Product Name
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
Brand Name
US-Strem
Product Number
14-1815
CAS
447440-43-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10333223
IUPAC Name
(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine
InChI Key
XHCRAANIMMYPDV-APBZJUGRSA-N
SMILES
CC@H1C@@H(OSi(N1C)(CC=C)Cl)C2=CC=CC=C2

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1. Strained silacycles in Organic Synthesis: A new reagent for the enantioselective allylation of aldehydes .
2. Enantioselective allylation of ketone-derived benzoylhydrazones: Practical synthesis of tertiary carbinamines. 3.Phenol-directed enantioselective allylation of aldimines and ketimines.
4. Enantioselective imidazole directed allylation of aldimines and ketimines.
References:
1.J. Am. Chem. Soc., 2002, 124, 7920 2.J. Am. Chem. Soc., 2004, 126, 5686 3.Org. Lett., 2006, 8, 6119
4.Org. L ett., 2007, 9, 3699

References

Allylation of Carbonyl Compounds and Imines

Publication Name: Science of Synthesis
Publication Date: 2020

Reaction of Allyltrichlorosilane with Amino Alcohols

Publication Name: Science of Synthesis
Publication Date: 2013

Using Chiral Allylsilane Reagents

Publication Name: Science of Synthesis
Publication Date: 2011

Using Chiral Allylsilane Reagents

Publication Name: Science of Synthesis
Publication Date: 2011

Synthesis of (–)-Dactylolide

Publication Name: Synfacts
Publication Date: 2010-09-22
DOI: 10.1055/s-0030-1258623