(S, R(p), S(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene, min. 97% JoSPOphos|26-1271|1221746-31-1

(S, R(p), S(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene, min. 97% JoSPOphos

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Sku SC26-1271_100_MG
US-Strem
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Product Information

Product Name
(S, R(p), S(SPO)-(1-t-Butylphosphinoyl)-2-1-(diphenylphosphino)ethylferrocene, min. 97% JoSPOphos
Brand Name
US-Strem
Product Number
26-1271
CAS
1221746-31-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71311013
IUPAC Name
(Z)-tert-butyl-2-(1S)-1-diphenylphosphanylethylcyclopenta-2,4-dien-1-ylidene-oxidophosphanium;cyclopenta-1,3-diene;iron(2+)
InChI Key
GKGAXSFACFRVDP-NTEVMMBTSA-N
SMILES
CC@@H(C\1=CC=C/C1=P+(\C(C)(C)C)/O-)P(C2=CC=CC=C2)C3=CC=CC=C3.CH-1C=CC=C1.Fe+2

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes :
1.Ligands used for the Rh-c atalyzed asymmetric hydrogenation of functionalized alkenes . 2.Ligands used for the Ru-c atalyzed asymmetric hydrogenation of ß-ketoesters.
3.Ligands used for the Rh-catalyzed as ymmetric hydrogenation of a-ketoesters .
Reference:
1.Angew. Chem. Int. Ed., 2010, 49, 6873.