1-{[(S)-Ferrocenyl-2-(R)-ethyl-1-dimethylamino)phenyl]-(S)-phosphino}-1'-dicyclohexylphosphinoferrocene, min. 97% Chenphos|26-1265|952586-19-5

1-{[(S)-Ferrocenyl-2-(R)-ethyl-1-dimethylamino)phenyl]-(S)-phosphino}-1'-dicyclohexylphosphinoferrocene, min. 97% Chenphos

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Sku SC26-1265_500_MG
US-Strem
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Product Information

Product Name
1-{(S)-Ferrocenyl-2-(R)-ethyl-1-dimethylamino)phenyl-(S)-phosphino}-1'-dicyclohexylphosphinoferrocene, min. 97% Chenphos
Brand Name
US-Strem
Product Number
26-1265
CAS
952586-19-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
92013030
IUPAC Name
cyclopenta-1,3-diene;1-2-cyclopenta-2,4-dien-1-yl(phenyl)phosphanylcyclopenta-2,4-dien-1-yl-N,N-dimethylethanamine;dicyclohexyl(cyclopenta-2,4-dien-1-yl)phosphane;bis(iron(2+))
InChI Key
RZHRELGUZPHGAM-UHFFFAOYSA-N
SMILES
CC(C-1C=CC=C1P(C-2C=CC=C2)C3=CC=CC=C3)N(C)C.C1CCC(CC1)P(C2CCCCC2)C-3C=CC=C3.CH-1C=CC=C1.Fe+2.Fe+2

Application

Technical Notes:
1.Ligand for the Rh- catalyzed highly enantios elective hydrogenation of a-oxy functionalized a,ß-uns acids in CF3CH2OH.
2.Ligand for the highly enantioselective Rh-catalyzed hydrogenation of 2-substituted-2-alkenols.
3.Ligand for the Rh-catalyzed asy mmetric hydrogenation of a-substituted cinnamic acids .
References:
1. Angew. Chem. Int. Ed., 2013, 52, 8652. 2.Chem. Commun., 2014, 50, 978.
3.Chem. Commun., 2016, 52, 2273.