1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF|26-0270|12150-46-8

1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF

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Sku SC26-0270_5_G
US-Strem
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Product Information

Product Name
1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF
Brand Name
US-Strem
Product Number
26-0270
CAS
12150-46-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15182658
IUPAC Name
bis(cyclopenta-1,4-dien-1-yl(diphenyl)phosphane);iron(2+)
InChI Key
KZPYGQFFRCFCPP-UHFFFAOYSA-N
SMILES
CH-1C=CC(=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.CH-1C=CC(=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Fe+2

Application

Technical Notes:
1. Ligand for Pd-catalyzed cross- coupling.
2. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
3.Ligand for Ni-catalyzed amination of aryl chlorides
4.Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles .
5.Ligand for Ni-catalyzed Suzuki reactions.
6.Ni-catalyzed hydroamination of 1,3-dienes.
7.Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
8. Pd-catalyzed y-arylation of ß,y-unsaturated ketones .
9. L igand for Ru-catalyzed reduction of nitriles to primary amines.
10. Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
11.Ligand for Rh-catalyzed cross-coupling (Ref. 12.Ligand for Rh-catalyzed olefin isomerization (Ref. 22).
13Ligand for Ni or Rh-catalyzed borylation (Ref. 23, 24)
14. Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.

References Data Source From Pubchem

A bioorthogonal nanosystem for imaging and in vivo tumor inhibition
Publication Name: Biomaterials
Publication Date: 2017-09
DOI: 10.1016/j.biomaterials.2017.05.036

Ru(II)/clotrimazole/diphenylphosphine/bipyridine complexes: Interaction with DNA, BSA and biological potential against tumor cell lines and Mycobacterium tuberculosis
Publication Name: Journal of Inorganic Biochemistry
Publication Date: 2016-09
DOI: 10.1016/j.jinorgbio.2016.06.023

Gold(I) complex of 1,1′-bis(diphenylphosphino) ferrocene–quinoline conjugate: a virostatic agent against HIV-1
Publication Name: Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine
Publication Date: 2016-02-27
DOI: 10.1007/s10534-016-9921-9

Aromatic amine N-oxide organometallic compounds: searching for prospective agents against infectious diseases.
Publication Name: Dalton transactions (Cambridge, England : 2003)
Publication Date: 2015-08-28
DOI: 10.1039/c5dt00557d

Hydrogenase biomimetics: Fe 2 (CO) 4 (μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst
Publication Name: Chemical communications (Cambridge, England)
Publication Date: 2014-01-28
DOI: 10.1039/c3cc46456c