1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, min. 98% (S,S)-f-Binaphane|26-0243|544461-38-3

1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, min. 98% (S,S)-f-Binaphane

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Sku SC26-0243_500_MG
US-Strem
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Product Information

Product Name
1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho1,2-c:2',1'-ephosphino}ferrocene, min. 98% (S,S)-f-Binaphane
Brand Name
US-Strem
Product Number
26-0243
CAS
544461-38-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
129827526
InChI Key
LKNXQPPPQGIJLC-UHFFFAOYSA-N
SMILES
C1C2=C(C3=CC=CC=C3C=C2)C4=C(CP1C5=CC=CCH5)C=CC6=CC=CC=C64.C1C2=C(C3=CC=CC=C3C=C2)C4=C(CP1C5=CC=CCH5)C=CC6=CC=CC=C64.Fe

Application

Technical Notes:
1.Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides 5 and cyclic N-
sulfonylimines 6
2.Enantioselective, asymmetric organocatalyst for 3+2 cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
3.Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%) 4.Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of a-imino anions.
5.Ligand used in iridium-catalyzed, asymm etric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).

References Data Source From Pubchem

Repotrectinib
Publication Name: Pharmaceutical Substances
Publication Date: 2025

Iridium-Catalyzed Asymmetric Hydrogenation
Publication Name: Iridium Catalysts for Organic Reactions
Publication Date: 2020
DOI: 10.1007/3418_2020_64

Asymmetric Reductive Amination
Publication Name: Stereoselective Formation of Amines
Publication Date: 2013
DOI: 10.1007/128_2013_484

Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics
Publication Name: Asymmetric Catalysis from a Chinese Perspective
Publication Date: 2011
DOI: 10.1007/978-3-642-19472-6_10

Iridium-Catalyzed Hydrogenation Using Phosphorus Ligands
Publication Name: Topics in Organometallic Chemistry
Publication Date: 2010-11-13
DOI: 10.1007/978-3-642-15334-1_2