(2R)-1-(11bR)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2-methyl-1,2,3,4-tetrahydroquinoline, 98%|15-7203|1186392-43-7

(2R)-1-(11bR)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2-methyl-1,2,3,4-tetrahydroquinoline, 98%

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Product Information

Product Name
(2R)-1-(11bR)-(Dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin-4-yl)-2-methyl-1,2,3,4-tetrahydroquinoline, 98%
Brand Name
US-Strem
Product Number
15-7203
CAS
1186392-43-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
44178476
IUPAC Name
(2R)-1-(12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)-2-methyl-3,4-dihydro-2H-quinoline
InChI Key
YFCZGDQGHCIHNB-HXUWFJFHSA-N
SMILES
CC@@H1CCC2=CC=CC=C2N1P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

Application

Technical Notes:
1. Chiral ligand used in the iridium-catalyzed formation of a chiral five membered ring spiroindolenine.
2.Chiral ligand used in an iridium-catalyzed, enantioselective, allylic alkylation reaction.
3. Chiral ligand used in the iridium-catalyzed, enantiose lective functional group substitution at the a-position ofß-ketoesters.
References:
1. J. Am. Chem. Soc., 2010, 132, 11419. 2.J. Am. Chem. Soc., 2013, 135, 10626. . 3.J.Am. Chem. Soc.. 2013, 135, 17298.

References Data Source From Pubchem

Stabilized Enolates as Nucleophiles
Publication Name: Science of Synthesis
Publication Date: 2023

Iridium-Catalyzed Asymmetric Allylic Amination of Indole- or Pyrrole-Tethered Allylic Carbonates
Publication Name: Science of Synthesis
Publication Date: 2021

Stereodivergent Allylic Alkylation/Fluorination of Acyclic Ketones
Publication Name: Synfacts
Publication Date: 2020-03-18
DOI: 10.1055/s-0040-1707642

Development of New Electrophiles in Palladium/Norbornene-Catalyzed ortho-Functionalization of Aryl Halides
Publication Name: Synlett
Publication Date: 2018-10-02
DOI: 10.1055/s-0037-1611057

Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account
Publication Name: Synlett : accounts and rapid communications in synthetic organic chemistry
Publication Date: 2018-08-15
DOI: 10.1055/s-0037-1610217