(2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-ethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)|15-6884|2247162-97-4

(2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-ethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

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Sku SC15-6884_500_MG
US-Strem
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Product Information

Product Name
(2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-ethyl-2,3-dihydrobenzod1,3oxaphosphole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6884
CAS
2247162-97-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138319722
IUPAC Name
(2S,3S)-3-tert-butyl-4-(2,6-dimethoxyphenyl)-2-ethyl-2H-1,3-benzoxaphosphole
InChI Key
MOKJPWHEQPXKKI-AVRWGWEMSA-N
SMILES
CCC@H1OC2=CC=CC(=C2P@@1C(C)(C)C)C3=C(C=CC=C3OC)OC

Application

Technical Notes: Ligand used with
1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
References:
1.Org. Lett. 2012, 14, 2258- 2261
2.J.Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148 4.Adv. Synth. Catal. 2016, 358, 3522-3527
5.ACS ( atal. 2018, 8, 10190-10209