(S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)|15-6880|2227217-19-6

(S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

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Sku SC15-6880_25_MG
US-Strem
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Product Information

Product Name
(S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzod1,3oxaphosphole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6880
CAS
2227217-19-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
134563031
IUPAC Name
(3S)-3-tert-butyl-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-1,3-benzoxaphosphole
InChI Key
GGPKISOMMZBCPQ-RUZDIDTESA-N
SMILES
CC1(OC2=CC=CC(=C2P@@1C(C)(C)C)C3=C(C=CC=C3OC)OC)C

Application

Technical Notes: L igand used with
1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
2.NickeI catalyst for asymmetric intramolecular/intermolecular reductive addition.
References:
1. Org. Lett. 2012, 14 , 2258 2261
2.J. Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148
4.Adv. Synth. Catal. 2016, 358, 3522-3527
5.ACS Catal. 2018, 8, 10190-10209
6.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524
7.Org. Chem. Front. 2015, 2, 1322-1325