(R)-3-(tert-Butyl)-4-(2-methoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 95%(>99% ee)|15-6872|1338454-28-6

(R)-3-(tert-Butyl)-4-(2-methoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 95%(>99% ee)

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Sku SC15-6872_500_MG
US-Strem
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Product Information

Product Name
(R)-3-(tert-Butyl)-4-(2-methoxyphenyl)-2,3-dihydrobenzod1,3oxaphosphole, min. 95%(>99% ee)
Brand Name
US-Strem
Product Number
15-6872
CAS
1338454-28-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
89586614
IUPAC Name
(3R)-3-tert-butyl-4-(2-methoxyphenyl)-2H-1,3-benzoxaphosphole
InChI Key
DGMHHZSVDWJVQF-NRFANRHFSA-N
SMILES
CC(C)(C)P@1COC2=CC=CC(=C21)C3=CC=CC=C3OC

Application

Technical Notes: Ligand used with
1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions. 2.Rhodium or palladium catalyzed asymmetric boration.
References:
1.Org. L ett. 2012, 14 , 2258- 2261
2.J. Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148 4.Adv. Synth. C atal.2016, 358, 3522-35 2 7
5.ACS Catal. 2018, 8, 10190-1 0209
6.J. Am. Chem. Soc. 2015, 137, 6746-6749 7.Chem. Sci. 201 7, 8, 5161-5165