2-((2R,3R)-3-(tert-Butyl)-4-methoxy-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)pyridine, 97% (>99% ee)|15-6858|1542796-07-5

2-((2R,3R)-3-(tert-Butyl)-4-methoxy-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)pyridine, 97% (>99% ee)

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Sku SC15-6858_25_MG
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Product Information

Product Name
2-((2R,3R)-3-(tert-Butyl)-4-methoxy-2,3-dihydrobenzod1,3oxaphosphol-2-yl)pyridine, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6858
CAS
1542796-07-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138319723
IUPAC Name
2-(2R,3R)-3-tert-butyl-4-methoxy-2H-1,3-benzoxaphosphol-2-ylpyridine
InChI Key
NFXZRUNTUSEVGQ-IIBYNOLFSA-N
SMILES
CC(C)(C)P@1C@@H(OC2=C1C(=CC=C2)OC)C3=CC=CC=N3

Application

Technical Notes:
1.Ligand used with Iridium catalyst for asymmetric hydrogenation of pydinium salts.
2.Ligand used with Iridium catalyst for asymmetric unfunctionalized alkenes.
References:
1.Org. L ett. 2018, 20, 1333-1337
2.Org. L ett. 2016, 18, 4920-4923
3.J. Am. Chem. Soc. 2016, 138, 15473-15481
4.J.Org. Chem. 2014,79, 993-1000
5.Angew. Chem. Int. Ed. 2014, 53, 14428 -14432