2-((2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)-6-methoxypyridine, 97% (>99% ee)|15-6856|2003230-67-7

2-((2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)-6-methoxypyridine, 97% (>99% ee)

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Sku SC15-6856_25_MG
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Product Information

Product Name
2-((2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzod1,3oxaphosphol-2-yl)-6-methoxypyridine, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6856
CAS
2003230-67-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138319724
IUPAC Name
2-(2S,3S)-3-tert-butyl-4-(2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphol-2-yl-6-methoxypyridine
InChI Key
OMRMWFIEDFJLAJ-DLLPINGYSA-N
SMILES
CC(C)(C)P@@1C@H(OC2=CC=CC(=C21)C3=C(C=CC=C3OC)OC)C4=NC(=CC=C4)OC

Application

Technical Notes: Ligand used with
1.Iridium catalyst for asymmetric hydrogenation of pydinium salts.
2.Iridium catalyst for asymmetric unfunctionalized alkenes.
References:
1.Org. Lett. 2018, 20, 1333-1337
2.Org. Lett. 2016, 18, 4920-4923
3.J. Am. Chem. Soc. 2016, 138, 4.J. Org. Chem. 2014, 79, 993-1000
5.Angew. Chem. Int. Ed. 2014, 53, 14428 -14432