2-((2S,3S)-3-(tert-Butyl)-4-methoxy-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)-6-methoxypyridine, 95% (>99% ee) (2S,3S)-MeO-BoQPhos|15-6854|1777796-37-8

2-((2S,3S)-3-(tert-Butyl)-4-methoxy-2,3-dihydrobenzo[d][1,3]oxaphosphol-2-yl)-6-methoxypyridine, 95% (>99% ee) (2S,3S)-MeO-BoQPhos

$188.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-6854_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
2-((2S,3S)-3-(tert-Butyl)-4-methoxy-2,3-dihydrobenzod1,3oxaphosphol-2-yl)-6-methoxypyridine, 95% (>99% ee) (2S,3S)-MeO-BoQPhos
Brand Name
US-Strem
Product Number
15-6854
CAS
1777796-37-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
117810572
IUPAC Name
2-(2S,3S)-3-tert-butyl-4-methoxy-2H-1,3-benzoxaphosphol-2-yl-6-methoxypyridine
InChI Key
YKAJTAYURKBDBW-SBUREZEXSA-N
SMILES
CC(C)(C)P@@1C@H(OC2=C1C(=CC=C2)OC)C3=NC(=CC=C3)OC

Application

Technical Notes: Ligand used with
1.Iridium catalyst for asymmetric hydrogenation of pydinium salts.
2.Iridium catalyst for asymmetric unfunctionalized alkenes.
References:
1.Org. Lett. 2018, 20, 1333-1337
2.Org. Lett. 2016, 18, 4920-4923
3.J. Am. Chem. Soc. 2016, 138, 4.J. Org. Chem. 2014, 79, 993-1000
5.Angew. Chem. Int. Ed. 2014, 53, 14428 -14432

References Data Source From Pubchem

Iridium-Catalyzed Asymmetric Hydrogenation of an Indenopyridine: 11β-HSD-1 Inhibitor
Publication Name: Synfacts
Publication Date: 2022-06-15
DOI: 10.1055/s-0041-1738395

Asymmetric Hydrogenation of 2-Arylpyridinium Salts
Publication Name: Synfacts
Publication Date: 2018-04-17
DOI: 10.1055/s-0037-1609677

Asymmetric Synthesis of an 11β-HSD-1 Inhibitor
Publication Name: Synfacts
Publication Date: 2017-01-18
DOI: 10.1055/s-0036-1589890

Iridium-Catalyzed Asymmetric Reduction of Pyridinium Salts
Publication Name: Synfacts
Publication Date: 2016-12-19
DOI: 10.1055/s-0036-1589720