(S)-3-(tert-Butyl)-4-(4',6'-dimethoxy-[1,1':3',1''-terphenyl]-5'-yl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)|15-6842|2021201-99-8

(S)-3-(tert-Butyl)-4-(4',6'-dimethoxy-[1,1':3',1''-terphenyl]-5'-yl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

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Sku SC15-6842_500_MG
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Product Information

Product Name
(S)-3-(tert-Butyl)-4-(4',6'-dimethoxy-1,1':3',1''-terphenyl-5'-yl)-2,3-dihydrobenzod1,3oxaphosphole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6842
CAS
2021201-99-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
134580262
IUPAC Name
(3S)-3-tert-butyl-4-(2,6-dimethoxy-3,5-diphenylphenyl)-2H-1,3-benzoxaphosphole
InChI Key
QNPLZIHZHBJCJB-PGUFJCEWSA-N
SMILES
CC(C)(C)P@@1COC2=CC=CC(=C21)C3=C(C(=CC(=C3OC)C4=CC=CC=C4)C5=CC=CC=C5)OC

Application

Technical Notes: 1.Ligand used with Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
2.Palladium catalyzed asymmetric C-H functionalizaiton.
References:
1.Org. Lett. 2012, 14 , 2258 2261
2.J. Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148 4.Adv. Synth. Catal. 2016, 358, 3522-352 7
5.ACS Catal. 2018, 8, 101 90-10209
6.doi.org/10.1016/j.tet.2019.03.038
7.Org. Chem. Front. 2015, 2, 1342-1345