(S)-3-(tert-Butyl)-4-(2,6-dimethoxy-3,5-dimethylphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)|15-6840|2021202-03-7

(S)-3-(tert-Butyl)-4-(2,6-dimethoxy-3,5-dimethylphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

$156.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-6840_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(S)-3-(tert-Butyl)-4-(2,6-dimethoxy-3,5-dimethylphenyl)-2,3-dihydrobenzod1,3oxaphosphole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6840
CAS
2021202-03-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
132534424
IUPAC Name
(3S)-3-tert-butyl-4-(2,6-dimethoxy-3,5-dimethylphenyl)-2H-1,3-benzoxaphosphole
InChI Key
HEETVIXTAXQITH-RUZDIDTESA-N
SMILES
CC1=CC(=C(C(=C1OC)C2=C3C(=CC=C2)OCP@3C(C)(C)C)OC)C

Application

Technical Notes: L igand used with
1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions .
2.Palladium catalyzed asymmetric C-H functionalizaiton.
References:
1.Org. Lett. 2012, 14 , 2258 -2261
2.J. Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148 4.Adv. Synth. Catal. 2016, 358, 3522-352 7
5.ACS Catal.2018, 8, 101 90-10209
6.doi.org/10.1016/j tet.2019.03.038 t
7. Org. Chem. Front. 2015, 2, 1342-1345

References Data Source From Pubchem

Enantioselective Arylation of Oxindoles Using Modified BI-DIME Ligands
Publication Name: Synthesis
Publication Date: 2018-06-28
DOI: 10.1055/s-0036-1591590

Ligand Effect on Diastereoselectivity in Suzuki–Miyaura Coupling
Publication Name: Synfacts
Publication Date: 2017-01-18
DOI: 10.1055/s-0036-1589875