(2R,3R)-3-(tert-Butyl)-4-(2,6-diisopropoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

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Sku SC15-6826_25_MG
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General Details
CAS #
SMILES
Chemical Purity
Molecular Formula C24H33O3P
Chemical Formula
Formula Weight 400.21
Reaction
Note
Physical Properties
Purity 97% (>99% ee)
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes: Ligand used with
1.Palladium catalyst for asymmetric Suzuki-Miyaura cross- coupling reactions. 2.Nickel catalyst for asymmetric intramolecular/intermolecular reductive addition.
References:
1.Org. Lett. 2012, 14 , 2258- 2261
2.J.Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148 4.Adv. Synth. Catal. 2016, 358, 3522-3527
5.AcS Catal. 2018, 8, 10190-10209
6.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524 7.Org. Chem. Front. 2015, 2, 1322-1325