(R)-3-(tert-Butyl)-4-(2,6-diphenoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)|15-6814|1441830-74-5

(R)-3-(tert-Butyl)-4-(2,6-diphenoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)

$747.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-6814_500_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(R)-3-(tert-Butyl)-4-(2,6-diphenoxyphenyl)-2,3-dihydrobenzod1,3oxaphosphole, 97% (>99% ee)
Brand Name
US-Strem
Product Number
15-6814
CAS
1441830-74-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71732754
IUPAC Name
(3R)-3-tert-butyl-4-(2,6-diphenoxyphenyl)-2H-1,3-benzoxaphosphole
InChI Key
XVXXWYLOBKSUEI-XIFFEERXSA-N
SMILES
CC(C)(C)P@1COC2=CC=CC(=C21)C3=C(C=CC=C3OC4=CC=CC=C4)OC5=CC=CC=C5

Application

Technical Notes: 1.Ligand used with Nickel catalyst for asymmetric intramolecular/intermolecular reductive addition. 2.Ruthenium catalyzed asymmetric addition.
3.Palladium catalyst for asymmetric intramolecular cyclization.
References:
1.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524 2.Org. Chem. Front. 2015, 2, 1322-1325
3.J. Org. Chem. 2013, 78, 6350-6355
4.Angew. Chem., Int. Ed. 2015, 54, 3033-3037 5.Tetrahedron.2016, 72, 1782- 1 786.

References Data Source From Pubchem

Enantioenriched Diarylcarbinols via Ru-Catalyzed Boronic Acid Addition of Aldehydes
Publication Name: Synfacts
Publication Date: 2013-08-19
DOI: 10.1055/s-0033-1339601