[2,4,6-Trimethoxyphenyl]dicyclohexylphosphonium tetrafluoroborate, 98% LB-PhosHBF4

[2,4,6-Trimethoxyphenyl]dicyclohexylphosphonium tetrafluoroborate, 98% LB-PhosHBF4

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Sku SC15-6520_500_MG
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General Details
Product Number 15-6520
CAS # 1217887-12-1
Molecular Formula C21H34BF4O3P
Formula Weight 452.27
Physical Properties
Purity 98%
Shipping & Stability
Safety Yes

Technical Notes:
1. Suzuki-coupling reaction of aryl or 1-alkenyl chlorides.
2. Suzuki-coupling reactions of substituted furans.
3. Highly selective Suzuki-coupling of C-CI bonds in ß-chlorobutenelides.
4.Palladium-catalyzed Suzuki-coupling reactions of chloroalkylidene-ß-lactones.
5. Suzuki-coupling reactions of chloro-substituted cyclopentadienylindoles.
6. Efficient synthesis of 4-halo-2,5 -dihydro-1 ,2-oxaphosphate-2-oxides from 1,2-allenylphosphates. 7. Palladium-catalyzed reaction of 2,3-allenoates with a 1,3-diketone.
8. Suzuki-coupling of chloro-substituted benzofurans with arylboronic acids.
9. Suzuki-coupling of 2-bromoalken-3-ols with alkylboronic acids.
10. Copper-catalyzed hydroboration of alkynamides with B2pin2.·
References:
1.Tetrahedron Lett., 2010, 51, 1284.
2.Chem. Commun., 2012, 48, 12074.
3.Chem. Eur. J., 2010, 16, 6434.
4.Org. Biomol. Chem., 2013, 11, 98.
5.Org. Lett., 2012, 14, 3616.
6.Eur. J. Org. Chem., 2012, 3806.
7.Eur. J. Org. Chem., 2012, 2585.
8.Org. Lett, 2012, 14, 720.
9.Eur. J. Org. Chem., 2012, 4034.
10.Org. Biomol. Chem., 2014, 12, 5945.