Product Name
2,4,6-Trimethoxyphenyldicyclohexylphosphonium tetrafluoroborate, 98% LB-PhosHBF4
Certificate of Analysis (COA)
IUPAC Name
dicyclohexyl-(2,4,6-trimethoxyphenyl)phosphanium tetrafluoroborate
InChI Key
KSZMPQYTYGNGTR-UHFFFAOYSA-O
SMILES
B-(F)(F)(F)F.COC1=CC(=C(C(=C1)OC)PH+(C2CCCCC2)C3CCCCC3)OC
Technical Notes:
1. Suzuki-coupling reaction of aryl or 1-alkenyl chlorides.
2. Suzuki-coupling reactions of substituted furans.
3. Highly selective Suzuki-coupling of C-CI bonds in ß-chlorobutenelides.
4.Palladium-catalyzed Suzuki-coupling reactions of chloroalkylidene-ß-lactones.
5. Suzuki-coupling reactions of chloro-substituted cyclopentadienylindoles.
6. Efficient synthesis of 4-halo-2,5 -dihydro-1 ,2-oxaphosphate-2-oxides from 1,2-allenylphosphates.
7. Palladium-catalyzed reaction of 2,3-allenoates with a 1,3-diketone.
8. Suzuki-coupling of chloro-substituted benzofurans with arylboronic acids.
9. Suzuki-coupling of 2-bromoalken-3-ols with alkylboronic acids.
10. Copper-catalyzed hydroboration of alkynamides with B2pin2.·
References:
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2.Chem. Commun., 2012, 48, 12074.
3.Chem. Eur. J., 2010, 16, 6434.
4.Org. Biomol. Chem., 2013, 11, 98.
5.Org. Lett., 2012, 14, 3616.
6.Eur. J. Org. Chem., 2012, 3806.
7.Eur. J. Org. Chem., 2012, 2585.
8.Org. Lett, 2012, 14, 720.
9.Eur. J. Org. Chem., 2012, 4034.
10.Org. Biomol. Chem., 2014, 12, 5945.