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Sku SC15-6520_500_MG
US-Strem
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Product Information

Product Name
2,4,6-Trimethoxyphenyldicyclohexylphosphonium tetrafluoroborate, 98% LB-PhosHBF4
Brand Name
US-Strem
Product Number
15-6520
CAS
1217887-12-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
46867874
IUPAC Name
dicyclohexyl-(2,4,6-trimethoxyphenyl)phosphanium tetrafluoroborate
InChI Key
KSZMPQYTYGNGTR-UHFFFAOYSA-O
SMILES
B-(F)(F)(F)F.COC1=CC(=C(C(=C1)OC)PH+(C2CCCCC2)C3CCCCC3)OC

Application

Technical Notes:
1. Suzuki-coupling reaction of aryl or 1-alkenyl chlorides.
2. Suzuki-coupling reactions of substituted furans.
3. Highly selective Suzuki-coupling of C-CI bonds in ß-chlorobutenelides.
4.Palladium-catalyzed Suzuki-coupling reactions of chloroalkylidene-ß-lactones.
5. Suzuki-coupling reactions of chloro-substituted cyclopentadienylindoles.
6. Efficient synthesis of 4-halo-2,5 -dihydro-1 ,2-oxaphosphate-2-oxides from 1,2-allenylphosphates. 7. Palladium-catalyzed reaction of 2,3-allenoates with a 1,3-diketone.
8. Suzuki-coupling of chloro-substituted benzofurans with arylboronic acids.
9. Suzuki-coupling of 2-bromoalken-3-ols with alkylboronic acids.
10. Copper-catalyzed hydroboration of alkynamides with B2pin2.·
References:
1.Tetrahedron Lett., 2010, 51, 1284.
2.Chem. Commun., 2012, 48, 12074.
3.Chem. Eur. J., 2010, 16, 6434.
4.Org. Biomol. Chem., 2013, 11, 98.
5.Org. Lett., 2012, 14, 3616.
6.Eur. J. Org. Chem., 2012, 3806.
7.Eur. J. Org. Chem., 2012, 2585.
8.Org. Lett, 2012, 14, 720.
9.Eur. J. Org. Chem., 2012, 4034.
10.Org. Biomol. Chem., 2014, 12, 5945.