(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX|15-1822|148461-14-7

(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX

$105.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-1822_50_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(S)-(-)-2-(2-(Diphenylphosphino)phenyl-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
Brand Name
US-Strem
Product Number
15-1822
CAS
148461-14-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
9807779
IUPAC Name
diphenyl-2-(4S)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-ylphenylphosphane
InChI Key
OUQSAXROROGQEE-JOCHJYFZSA-N
SMILES
CC(C)C@H1COC(=N1)C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4

Application

Technical Notes:
1. Chiral ligand used in the asymmetric reduction of highly substituted olefins
2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to
the fact that the catalytic system does not promote double bond isomerization.
2.Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole . 3.Decarboxylative allylic alkylation.
References:
1. Angew. Chem. Int. Ed., 1998, 37, 2897. 2. Angew. Chem. Int. ., 1996, 35, 200. 3. Acc. Chem. Res. 2000, 33, 336. 4. Eur. J. Org. Chem.. 2011, 31, 6288. 5. Org. Lett., 2014, 16, 118.

References Data Source From Pubchem

(4+1)-Cycloadditions Exploiting the Biphilicity of Oxyphosphonium Enolates and RhII/PdII-Stabilized Metallocarbenes for the Construction of Five-Membered Frameworks
Publication Name: Synlett
Publication Date: 2021-01-26
DOI: 10.1055/s-0040-1706009

Recent Developments in Asymmetric Allylic Amination Reactions
Publication Name: Synthesis
Publication Date: 2016-08-17
DOI: 10.1055/s-0035-1562090

An Investigation of the Asymmetric Huisgen ‘Click’ Reaction1
Publication Name: Synlett
Publication Date: 2013-11-05
DOI: 10.1055/s-0033-1340152

Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazolide
Publication Name: Synfacts
Publication Date: 2012-01-19
DOI: 10.1055/s-0031-1290022

Selective Nucleophilic Fluoroalkylations Facilitated by Removable Activation Groups
Publication Name: Synlett
Publication Date: 2011-03-15
DOI: 10.1055/s-0030-1259906