(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Bis(3,5-di-t-butylphenyl)propane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole) (S,R)-BDTBIn-SaBOX|07-1228|1435467-29-0

(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Bis(3,5-di-t-butylphenyl)propane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole) (S,R)-BDTBIn-SaBOX

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Product Information

Product Name
(3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Bis(3,5-di-t-butylphenyl)propane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno1,2-doxazole) (S,R)-BDTBIn-SaBOX
Brand Name
US-Strem
Product Number
07-1228
CAS
1435467-29-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71739082
IUPAC Name
(3aR,8bS)-2-2-(3aR,8bS)-4,8b-dihydro-3aH-indeno1,2-d1,3oxazol-2-yl-1,3-bis(3,5-ditert-butylphenyl)propan-2-yl-4,8b-dihydro-3aH-indeno1,2-d1,3oxazole
InChI Key
WVVLVBHMBBXGQX-QHQGJXSCSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1)CC(CC2=CC(=CC(=C2)C(C)(C)C)C(C)(C)C)(C3=NC@@H4C@H(O3)CC5=CC=CC=C45)C6=NC@@H7C@H(O6)CC8=CC=CC=C78)C(C)(C)C

Application

Technical Note:
1. Ligand used in the copper-catalyzed, highly enantioselective cyclopentannulation of indoles with donor- acceptor cyclopropanes.
Reference:
1. J. Am. Chem. Soc., 2013, 135, 7851.

References Data Source From Pubchem

Copper-Catalyzed [3+1] Cycloaddition to Form Substrates for α-Amino Acid Synthesis
Publication Name: Synfacts
Publication Date: 2020-03-18
DOI: 10.1055/s-0039-1690061