Dichloro[(R)-(+)-2,2'-bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl]palladium(II)|46-0188|1338245-54-7

Dichloro[(R)-(+)-2,2'-bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl]palladium(II)

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Sku SC46-0188_250_MG
US-Strem
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Product Information

Product Name
Dichloro(R)-(+)-2,2'-bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenylpalladium(II)
Brand Name
US-Strem
Product Number
46-0188
CAS
1338245-54-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
139116716
IUPAC Name
2-2-bis(furan-2-yl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(furan-2-yl)phosphane;palladium(2+);dichloride
InChI Key
BMAYXCQGBAXDRD-UHFFFAOYSA-L
SMILES
COC1=C(C(=CC=C1)P(C2=CC=CO2)C3=CC=CO3)C4=C(C=CC=C4P(C5=CC=CO5)C6=CC=CO6)OC.Cl-.Cl-.Pd+2

Application

Technical Notes:
1.This Palladium- complex is used for the asymmetric cross- coupling of allylboron reagents with allylic ele ctrophiles. 2.The catalyst is used for the kinetic resolution of propargylic acetates to give enantioenriched 1,5-enynes.
References:
1.J Am Chem. Soc.. 2014.136. 7092.
2.AdvSynth. Catal., 2013, 355, 3413.