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Sku 15-1787-250MG
STREM
| Technical Notes： 1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1) 2.With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines . 3.With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media. References: 1.Angew. Chem. Int. Ed.. 2004, 43, 5971. 2.Org. Lott 2006.8, 2437. 3.J. Am. Chom. Soc.2005, 127. 9682. |
