$119.00
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Sku 15-1056-250MG
STREM
| Technical Notes: 1. Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls, and imines. 2.Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes . 3. Ligand used in the iridium-c atalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines. 4.Asymmetric Cu catalyzed propargylic substitution with amines,a and enamines. 5.Catalytic desymmetrizing intramolecular Heck reaction. 6.Assembly of 1,3-polyols. 7.Pd-catalyzed diastereo/enantios elective allylic alkylations of ketone enolates . 8.Enantios elective vinylogous R eformatsky-type addition. 9. Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron- substituted allylcopper complexes and their In situ site-, diastereo-, and enantios elective additions to ketones . |
