(S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (S)-Cl-MeO-BIPHEP

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Sku 15-1056-250MG
STREM
Technical Notes:
1. Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls,
and imines.
2.Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes .
3. Ligand used in the iridium-c atalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines.
4.Asymmetric Cu catalyzed propargylic substitution with amines,a and enamines.
5.Catalytic desymmetrizing intramolecular Heck reaction.
6.Assembly of 1,3-polyols.
7.Pd-catalyzed diastereo/enantios elective allylic alkylations of ketone enolates .
8.Enantios elective vinylogous R eformatsky-type addition.
9. Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron- substituted allylcopper complexes
and their In situ site-, diastereo-, and enantios elective additions to ketones .