(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(S)-3,5-xylyl-PHANEPHOS

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Sku 15-0731-500MG
STREM
Technical Notes:
1.See 15-0426
2.Chiral ligand employed in the enantioselective hydrogenation of various ketones.
3.Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
4.Chiral ligand employed in the enantioselective [2 +2] cycloaddition of oxa bicyclic alkenes with terminal alkynes.  5.Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes. 
References:
1.Org. L ett., 2000, 2, 4173.
2.Angew. Chem. Int. Ed., 2010, 49, 9197.
3.Org. L ett., 2010, 12, 304.
4Nature Chemistry, 2012, 4, 405.