Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98%|79-1200|852445-81-9

Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98%

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Sku SC79-1200_500_MG
US-Strem
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Product Information

Product Name
Chloro1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidenegold(I), 98%
Brand Name
US-Strem
Product Number
79-1200
CAS
852445-81-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71310802
IUPAC Name
1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene-chlorogold
InChI Key
YFUIKJIITPMUAT-UHFFFAOYSA-M
SMILES
CC1=CC(=C(C(=C1)C)N2C=CN(C2=AuCl)C3=C(C=C(C=C3C)C)C)C

Application

Technical Notes:
1.Catalyst for the rearrangement of alkynyl sulfoxides to benzothie pinones
2.Catalyst for the rearrangement of homopropargylic ethers to a,ß-unsaturated carbonyl compounds
3. Catalyst for oxidative cyclopropanation of N-Allylynamides to 3-aza-bicyclo3. 1.O-hexan-2 - one derivatives 4. Catalyst for oxidative rearrangement of homopropargylic ethers to cyclobutanones
References:
1.J. Am. Chem. Soc., 2007, 129, 4160 2.Org. Lett., 2012, 14, 4902
3.Org. Lett., 2013, 15, 2374
4.Adv. Synth. Catal., 2013, 355, 2488

References Data Source From Pubchem

Synthesis of N-heterocyclic carbene gold(I) complexes
Publication Name: Nature Protocols
Publication Date: 2021-01-27
DOI: 10.1038/s41596-020-00461-6

A heterometallic ruthenium–gold complex displays antiproliferative, antimigratory, and antiangiogenic properties and inhibits metastasis and angiogenesis-associated proteases in renal cancer
Publication Name: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry
Publication Date: 2018-03-05
DOI: 10.1007/s00775-018-1546-8