[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%|79-0245|951776-24-2

[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%

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Sku SC79-0245_500_MG
US-Strem
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Product Information

Product Name
1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidenebis(trifluoromethanesulfonyl)imidegold(I), min. 95%
Brand Name
US-Strem
Product Number
79-0245
CAS
951776-24-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138962334
IUPAC Name
1,3-bis2,6-di(propan-2-yl)phenyl-2H-imidazol-2-ide;bis(trifluoromethylsulfonyl)azanide;gold
InChI Key
SRNIVRFMRMHJTC-UHFFFAOYSA-N
SMILES
CC(C)C1=C(C(=CC=C1)C(C)C)N2CH-N(C=C2)C3=C(C=CC=C3C(C)C)C(C)C.C(F)(F)(F)S(=O)(=O)N-S(=O)(=O)C(F)(F)F.Au

Application

Technical Notes:
1. Gold catalyst used for the hydroarylating cyclization of 1 ,2 bis(2-iodoethynyl)benzenes. 2. Gold catalyst used for the carbocyclization of phenols with a terminal alkyne.
3.Intermolecular C-H activation through the gold(I)-catalyzed reaction of iodoalkynes. 4. Reaction of ynamide with benzyl azides.
References:
1. Adv. Synth. Catal, 2015, 357, 500.
2.Adv. Synth. Catal., 2014 356, 2417.
3.Angew. Chem. Int. Ed., 2015, 54, 3052.
4. J. Am. Chem. Soc., 2015, 137, 9567.

References Data Source From Pubchem

Synthesis from Silylketenes
Publication Name: Science of Synthesis
Publication Date: 2020

Synthesis of Carbazoles and Indolines by Gold-Catalyzed Diels–Alder Reactions
Publication Name: Synfacts
Publication Date: 2019-03-19
DOI: 10.1055/s-0037-1612374

Diastereoselective Gold(I)-Catalyzed [2+2+2] Cycloaddition of Oxo-1,5-enynes
Publication Name: Synthesis
Publication Date: 2016-07-19
DOI: 10.1055/s-0035-1562452

Intermolecular[3 + 2]and[4 + 3]Cycloadditions of Propargyl Carboxylates and Alkenes or Dienes
Publication Name: Science of Synthesis
Publication Date: 2012

1,3-Dipolar Cycloadditions
Publication Name: Science of Synthesis
Publication Date: 2012