[mu-Bis(diphenylphosphino)methane]dichlorodigold(I), 99%|79-0115|37095-27-5

[mu-Bis(diphenylphosphino)methane]dichlorodigold(I), 99%

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Sku SC79-0115_1_G
US-Strem
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Product Information

Product Name
mu-Bis(diphenylphosphino)methanedichlorodigold(I), 99%
Brand Name
US-Strem
Product Number
79-0115
CAS
37095-27-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11700690
IUPAC Name
chlorogold;diphenylphosphanylmethyl(diphenyl)phosphane
InChI Key
JNPUWTQJFLJEJC-UHFFFAOYSA-L
SMILES
C1=CC=C(C=C1)P(CP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.ClAu.ClAu

Application

Technical Notes:
1. Catalyst used with chiral counter-ion for asymmetric hydroalkoxylation. 2. Catalyst used for intramolecular acetylene Schmidt reaction.
References:
1. Science, 2007, 31 7, 496.
2.J. Am. Chem. Soc., 2005, 127, 1 1260.

References

Intramolecular Oxidation of Alkynes
Publication Name: Science of Synthesis
Publication Date: 2017

Crystalline-Amorphous-Crystalline Transformation in a Highly Brilliant Luminescent System with Trigonal-Planar Gold(I) Centers
Publication Name: Scientific Reports
Publication Date: 2016-05-17
DOI: 10.1038/srep26002

Silver–Gold Heterobimetallic Catalysis
Publication Name: Science of Synthesis
Publication Date: 2016

Exceptionally fast carbon-carbon bond reductive elimination from gold(III).
Publication Name: Nature Chemistry
Publication Date: 2013-12-22
DOI: 10.1038/nchem.1822

Cyclization of Alk-3-ynylamines and Homopropargyl Azides
Publication Name: Science of Synthesis
Publication Date: 2013