Hydrido(dimethylphosphinous acid-kP)[hydrogen bis(dimethylphosphinito-kP)]platinum(II) Ghaffar-Parkins catalyst

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Sku SC78-0725_2_G
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General Details
CAS # 173416-05-2
SMILES
Chemical Purity
Molecular Formula C6H21O3P3Pt
Chemical Formula
Formula Weight 429.23
Reaction
Note
Physical Properties
Purity
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Note:
1. Widely used in complex multi-step organic syntheses. This mild hydration catalyst converts hindered and acid/base sensitive nitriles to amides. The amide is released from the metal coordination sphere preventing further hydrolysis to acid. Typically . turnover frequency (TOF) ranges from 16 to 380 h-1 depending on steric factors. For optimal results avoid the presence of coordinating anions especially cyanide and halide.
References:
1.J.Org.Chem.2004, 69, 2327.
2.Org. Lett, 2006. 8. 2643
3.J. Org Chem.. 2009. 74. 5405. 4.Tetrahedron Lett.，2010，51，6422
5. Appl. Sci. 2015, 5, 380. (catalyst review article)