Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

Technical Notes:
1.Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via
enantioselective c-c Bond cleavage.
2.Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).
4.Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2'- biphenylylene ditriflates .
4. Paladium catalyst for regio- and enantioselective allylic alkylation of ketones through allyl enol carbonates .
5.Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.
6.Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed
trimethylenemethane-[3 +2]-cycloaddition.
7. Usewd for Pd-catalyzed insertion of a diazoesters into vinyl halides to generate a,ß-unsaturated Y amino
Esters.
8.Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates .
9.Palladium catalyst for asymmetric addition of oxindoles and allenes
10. Catalyst for diastereo- and enantioselective formal [3+ 2]-cycloaddition between substituted
vinylcyclopropanes and electron-deficient olefins.
11. Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael
sacceptors.
12. Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered
heterocycles.