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Sku SC46-0100_10_G
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General Details
Product Number 46-0100
CAS # 12012-95-2
SMILES
Chemical Purity
Molecular Formula [C3H5PdCl]2
Chemical Formula
Formula Weight 365.86
Reaction
Note
Physical Properties
Purity min. 98%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold Store at 2-8℃
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.Precatalyst for the enantioselective hydrosilylation of olefins.
2.Precatalyst for asymmetric allylic alkylation and amination.
3.Used as a palladium source for cross-coupling reactions .
4. Can be used with Trost ligands.
5. Catalyst for the carbostannylation of alkynes.
6. Used as a precatalyst for a-arylation of aldehydes.
References:
1.J. Am. Chem. Soc., 1991, 1 13, 9887.
2.Tetrahedron, 1994, 50, 335.
3.J. Am. Chem. Soc., 2007, 129, 7718.
4. Org. L ett., 2007, 9, 4295.
5. Org. L ett., 2008, 10, 501.
6. Org. L ett., 2005, 7, 945.
7.Synlett, 2005, 2057
8. Tetrahedron, 2007, 63, 9393.
9. J. Am. Chem. Soc., 2006, 128, 2540.
10.Org. L ett., 2006, 8, 2027.
11.Angew. Chem. Int. Ed., 2007, 46, 6123.
12.J. Am. Chem. Soc., 1998, 120, 2975.
13.Angew. Chem. Int. Ed., 2008, 47, 2127.
14.Chem. Rev., 1996, 96, 395. (review)
15.Science of Synthesis, 2002, 1, 1 13.