Product Name
Chlorotris(triphenylphosphine)cobalt(I), min. 98%
Certificate of Analysis (COA)
IUPAC Name
cobalt;tris(triphenylphosphane);chloride
InChI Key
LNEYYSPXDKDADL-UHFFFAOYSA-M
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl-.Co
Storage Condition
Store at 2-8℃
Technical Notes:
1. Cobalt(I)-catalyzed, steroselective olefination of alkylzinc reagents with aryl aldehydes.
2.Reagent for the reductive radical dimerization of 3-haloindoline derivatives .
3. Cobalt-catalyzed, asymmetric addition of silylacetylene to 1, 1-disubstituted allenes.
References:
1. Synthesis, 2003, 1506.
2.J. Am. Chem. Soc., 2010, 132, 14376.
3. J. Org. Chem., 2013, 78, 8986.
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