(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate monohydrate|27-0528|672306-06-8

(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate monohydrate

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Sku SC27-0528_5_G
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Product Information

Product Name
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(III) p-toluenesulfonate monohydrate
Brand Name
US-Strem
Product Number
27-0528
CAS
672306-06-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138991599
IUPAC Name
cobalt(3+);2,4-ditert-butyl-6-(1S,2S)-2-(3,5-ditert-butyl-2-oxidophenyl)methylideneaminocyclohexyliminomethylphenolate;4-methylbenzenesulfonate
InChI Key
VPVIMRWIBFMDDY-ARDORAJISA-K
SMILES
CC1=CC=C(C=C1)S(=O)(=O)O-.CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O-)C=NC@H2CCCCC@@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O-.Co+3

Application

Technical Notes:
1. Useful catalyst for the enantiospecific addition of carbon dioxide to propylene oxide.
2.Catalyst used for the direct synthesis of optically active propylene carbonate from racemic epoxides . References: 1.Org. Let, 2006, 8, 4401
2. J. Am. Chem. Soc., 2006, 126, 3732.