$156.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC08-1270_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(1S,2R)-2-Phenyl-1-cyclohexanol, 98%, (99% ee)
Brand Name
US-Strem
Product Number
08-1270
CAS
34281-92-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
9898975
IUPAC Name
trans-(1S,2R)-2-phenylcyclohexan-1-ol
InChI Key
AAIBYZBZXNWTPP-NEPJUHHUSA-N
SMILES
C1CCC@@H(C@H(C1)C2=CC=CC=C2)O

Application

Technical Notes:
1.Used for synthesis of corresponding ketone via 2 -iodoxybenzenesulfonic acid catalyzed selective oxidation.
2.Used for the asymmetric synthesis of H-phosphinate esters.
3.Used in total synthesis of natural products e .g. pyrrolizidinones.
4.Reagent for synthesis of diaryl phosphinates having cyclohexyloxy chiral auxiliaries used in Ir-catalyzed c -H amidation of arylphosphoryls.
5.Component of the pentacarboxycyclopentadiene Brønsted acid catalyst used for an enantioselective catalytic inverse electron-demand Diels-Alder reaction of salicylaldehyde acetal-derived oxocarbenium ions and vinyl ethers to generate 2,4-dioxychromanes is described .

References

Oxidation of Secondary Alcohols to Ketones

Publication Name: Science of Synthesis
Publication Date: 2022

Single-Electron-Transfer Reduction of Epoxides

Publication Name: Science of Synthesis
Publication Date: 2020

Electrophilic Ring Opening of Small Heterocycles

Publication Name: Synthesis
Publication Date: 2017-08-30
DOI: 10.1055/s-0036-1589102

Kinetic Resolution of Secondary Alcohols Using Nitroxyl Radical Based Systems

Publication Name: Science of Synthesis
Publication Date: 2017

Nickel Co-catalyzed Epoxide Ring Opening with Aryl Halides

Publication Name: Synfacts
Publication Date: 2014-03-18
DOI: 10.1055/s-0033-1340930