(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)|14-1810|680592-40-9

(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)

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Sku SC14-1810_1_G
US-Strem
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Product Information

Product Name
(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
Brand Name
US-Strem
Product Number
14-1810
CAS
680592-40-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
53470558
IUPAC Name
(2S,4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine
InChI Key
NSZWPVQENFHZEA-SCGJFBFUSA-N
SMILES
CC@H1C(OSi@@(N1C)(C2=CC=CC=C2)Cl)C3=CC=CC=C3

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1.Reagent used in the enantioselective Friedel-Crafts alkylations with benzoylhydrazones . 2. Reagent used in highly enantioselective 3+2 acylhydrazone-enol ether cycloadditions.
References:
1. J. Am. Chem. Soc., 2005, 127, 2858.
2.J. Am. C hem. Soc., 2005, 127, 9974
3.Angew. Chem. Int. Ed., 2009, 48, 2403 .
4.J. Am. Chem. Soc., 2009, 131, 14638.
5.Org. L ett., 2012, 14, 2610.