1-{[(R)-Ferrocenyl-2-(S)-ethyl-1-dimethylamino)phenyl]-(R)-phosphino}-1'-dicyclohexylphosphinoferrocene, min. 97% Chenphos|26-1266|1036373-39-3

1-{[(R)-Ferrocenyl-2-(S)-ethyl-1-dimethylamino)phenyl]-(R)-phosphino}-1'-dicyclohexylphosphinoferrocene, min. 97% Chenphos

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Sku SC26-1266_2_G
US-Strem
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Product Information

Product Name
1-{(R)-Ferrocenyl-2-(S)-ethyl-1-dimethylamino)phenyl-(R)-phosphino}-1'-dicyclohexylphosphinoferrocene, min. 97% Chenphos
Brand Name
US-Strem
Product Number
26-1266
CAS
1036373-39-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71311009
IUPAC Name
cyclopenta-1,3-diene;(1S)-1-2-cyclopenta-2,4-dien-1-yl(phenyl)phosphanylcyclopenta-2,4-dien-1-yl-N,N-dimethylethanamine;dicyclohexyl(cyclopenta-2,4-dien-1-yl)phosphane;bis(iron(2+))
InChI Key
RZHRELGUZPHGAM-CCABKTBBSA-N
SMILES
CC@@H(C-1C=CC=C1P(C-2C=CC=C2)C3=CC=CC=C3)N(C)C.C1CCC(CC1)P(C2CCCCC2)C-3C=CC=C3.CH-1C=CC=C1.Fe+2.Fe+2

Application

Technical Note:
1.Ligand used for the Rh-catalyzed asymmetric hydrogenation of a-substituted acrylic acids.
2.Ligand for Rh-Catalyzed Enantioselective Hydrogenation of a-Oxy Functionalized a,ß-L Jnsaturated Acids.
Reference:
1.Patent number US 8,106,227 B2.
2. Chem. Commun., 2016, 52, 2273-2276.