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Sku SC45-0650_1_G
US-Strem
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Product Information

Product Name
Chlorotris(triphenylphosphine)rhodium(I), 99% WILKINSON'S CATALYST
Brand Name
US-Strem
Product Number
45-0650
CAS
14694-95-2
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1A homogeneous hyd rogenation catalyst which operates under mild cond itions .
2.Catalyst for the decarbonylation of aldehydes .
3.Catalyst for regio- and stereoselective allylic substitution reactions.
4.Alkyne hydro-phos phorylation
5.Heck-type reaction with a, ß-unsaturated esters.
6.Rh(l)-catalyzed ortho-alkenylation of aromatic ketimines with alkynes
7.Allylic alcohol-olefin cou pling.
8.Terminal alkenes from ketone s .
9.Rh-catalyzed isomerization of a-aryl propargyI alcohols to indanones.
11.Reductive de protection of silyl groups .
Intramolecular carbo-acylation reaction.
12.Rearrangement of 3-iminocyclopropenes.
13.Reductive a acylation of enones to form 1 ,3-diketones.
14Rh-catalyzed C-H activation/cycloisome rization.
15.Rh-catalyzed [2+2+2] cycloaddition.
16. Cross-coupling of alcohols at ß-position with aldehydes.