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Sku SC44-0181_5_G
US-Strem
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Product Information

Product Name
Diacetato{(S)-(+)-5,5'-bisdi(3,5-di-t-butyl-4-methoxyphenyl)phosphino-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2(S)-dtbm-segphos?
Brand Name
US-Strem
Product Number
44-0181
CAS
1025476-84-9
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS ligand, as the ruthenium complex, gives superior
ena ntioselectivity and dias te re oselectivity in the asymmetric hydrogenation of a-subs tituted- ß-ke toesters. See 1 5-0066
2.Ruthenium catalyzed enantioselective synthesis of ß amino acids by hyd rogenation
3.Ruthenium catalyzed asymmetric hydrogenation of 3 quinuclidinone. See 44-0098 for Ru catalyst.
References:
1. WIPO Pat. WO20050284 19.
2. u.S. Pat. App.2006047122.