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Sku SC44-0017_500_MG
US-Strem
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Product Information

Product Name
Acetonitrile(cyclopentadienyl)2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1H-imidazoleruthenium(II) hexafluorophosphate, min. 98% Alkene Zipper Catalyst
Brand Name
US-Strem
Product Number
44-0017
CAS
930601-66-4
Certificate of Analysis (COA)​
COA not found

Application

Technical Note:
1."Zipper" catalyst for alkene isomerization over up to 30 double bond positions (Ref. 1). Selective isomerization over one position also possible (Ref. 2, 3). Depending on substrate structure, H/D exchange at accessible allylic positions can be accompanied by is omerization (Ref. 4).
References :
1. J Am. Chem. Soc..2007, 129, 9592. 2.Topics in Catalysis, 2010, 53, 1015. 3. J. Am. Chem. Soc.2012, 134, 10357.