| CAS # | 849950-53-4 |
| SMILES | |
| Chemical Purity | |
| Molecular Formula | [Rh(C8H12)(C34H36P2)]BF4ae |
| Chemical Formula | |
| Formula Weight | 804.49 |
| Reaction | |
| Note |
$552.00
Available on backorder. No lead time available. Please request a quote.
Sku SC45-0202_500_MG
US-Strem
General Details
Physical Properties
| Purity | min. 98% |
| Density | |
| Melting Point | |
| Boiling Point | |
| Flash Point | |
| Vapor Pressure | |
| Surface Area | |
| Pore Volume | |
| Specific Rotation |
Shipping & Stability
| Safety | Yes |
| Store Cold | |
| Dry Ice | |
| Alternative Product for Air Shipment | |
| Export Limitations | |
| Pyrophoric | |
| Hygroscopic | |
| Air Sensitive | |
| Light Sensitive | |
| Heat Sensitive | |
| Moisture Sensitive | |
| Odorous Material |
Technical Notes:
1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
References:
1. Org. Lett., 2003, 5, 1273.
2. Tetrahedron Lett, 2004, 45, 9277.
3. Angew. Chem. Int. Ed., 2005, 44, 5834.
