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Sku 45-0201-2G
STREM
| Technical Notes: 1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalyzed asymmetric hydrogenation. 2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides. 3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents. 4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins. References: 1. Org. Lett., 2003, 5, 1273. 2. Tetrahedron Lett., 2004, 45, 9277. 3. Angew. Chem. Int. Ed., 2005, 44, 5834. |
